<!DOCTYPE html>
<html>
<head>
<script type='text/javascript'
src='http://ajax.googleapis.com/ajax/libs/jquery/1.7.2/jquery.min.js'></script>
<script type='text/javascript'>
$(window).load(function(){
console.log($('ul:eq(1) > li').text())
});
</script>
</head>
<body>
<ul>
<li>Sample</li>
<li>Sample</li>
<li>Sample</li>
<li>
<ul>
<li>Need to Get access to this li</li>
</ul>
</li>
<li>Sample</li>
</ul>
</body>
</html>